Nope... it'll be one of the element / compounds that changes phase from liquid to gas around 65 degrees and 1-6psi.... for part 3 for sure, and more than likely for the others as well. Are you limited to elements, or can you use compounds as well?
I don't have my handbook of chemistry and physics handy, it's too damn big to carry around, so I can't really look up squat at the moment. If I had to guess at a compound, I'd likely pick tetrafluoroethane, commonly known as R134a, or the refridgerant we use in air conditioning system. (Actually, I might be tempted to pick R12, as it was more efficient than R134a IIRC.) These are the types of conditions that our AC systems are designed to run on, after all. The only problem I can forsee is that there could easily be some compounds that are far more efficient, but are not used due to cost or environmental factors.
Heats up the most is a little bit vague - do you mean gains more energy or do you mean sheds excess heat?